8-Hydroxy-2-methylquinolinium dichlorido(2-methylquinolin-8-olato-κ2N,O)zincate acetonitrile disolvate

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8-Hy­droxy-2-methyl­quinolinium dichlorido(2-methyl­quinolin-8-olato-κ2 N,O)zincate acetonitrile disolvate

The reaction of 2-methyl-8-hy-droxy-quinoline and zinc chloride in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[Zn(C(10)H(8)NO)Cl(2)]·2CH(3)CN, in which the Zn(II) atom is coordinated by an- N,O-chelating 2-methyl-quinolin-8-olate ligand and two chloride ligands in a distorted tetra-hedral geometry. The cation is linked to the heterocyclic anion by an O-H⋯O hydrogen bond and the...

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8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ2 N,O)zincate acetonitrile mono­solvate

The reaction of 2-methyl-8-hy-droxy-quinoline and zinc bromide in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)CN, in which the Zn(II) ion is coordinated by a N,O-chelating 2-methyl-quinolin-8-olate ligand and two bromide ligands in a distorted tetra-hedral geometry. The cation is linked to the anion by an O-H⋯O hydrogen bond and the quinolinium H atom...

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8-Hydr­oxy-2-methyl­quinolinium tetra­chlorido(quinolin-8-olato-κ2 N,O)stannate(IV) acetonitrile monosolvate

In the title solvated salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·CH(3)CN, the Sn(IV) atom is chelated by the N,O-bidentate 8-hydroxy-quinolinate ligand and four chloride ions, generating a distorted SnONCl(4) octa-hedral coordination geometry for the metal. In the crystal, the cations are linked to the anions and the solvent mol-ecules by O-H⋯O and N-H⋯N hydrogen bonds, respectively.

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8-Hy­droxy-2-methyl­quinolinium tetra­chlorido(quinolin-2-olato-κ2 N,O)stannate(IV) methanol disolvate

In the reaction of 8-hy-droxy-quinoline, 2-methyl-8-hy-droxy-quinoline and stannic chloride, the 2-methyl-8-hy-droxy-quinoline is protonated, yielding the disolvated title salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·2CH(3)OH. The Sn(IV) atom in the anion is N,O-chelated by the hy-droxy-quinolinate in a cis-SnNOCl(4) octa-hedral geometry. In the crystal, the cation, anion and solvent mol-ecules ar...

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8-Hydroxy-2-methylquinoline

The asymmetric unit of the title compound, C(10)H(9)NO, contains two independent mol-ecules which are linked by a pair of O-H⋯N hydrogen bonds into a hydrogen-bonded dimer.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811032338